Novel carbon-carbon bond formation reaction at the C-4 position of an azetidin-2-one by means of radical cyclization
β Scribed by Kametani, Tetsuji; Chu, Shih Der; Itoh, Akira; Maeda, Sayuri; Honda, Toshio
- Book ID
- 127173182
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 736 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0022-3263
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Addition of carbon radicals generated from organoselenium reagents P SeR: R= COPh, CO\*Et, CH,CO,Et, CH2COMe, and CH,CN) to 4',5'-unsaturated uraciinucleosides was found to provide a highly efficient entry to C-C bond formation at the 5'-position, the stereochemical outcome of which is dependent upo