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Novel Carbanionic Polymerization of Methyl Methacrylate by Unusual Electron-Transfer Catalysis

✍ Scribed by Janeczek, Henryk; Jedliñski, Zbigniew; Bosek, Izabela


Book ID
126783180
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
108 KB
Volume
32
Category
Article
ISSN
0024-9297

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Polymerization of methyl methacrylate by
✍ Aradhana Goswami; Shashi D. Baruah; Narendra N. Dass 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 615 KB

The kinetics of charge-transfer (CT) polymerization of methyl methacrylate (MMA) in the presence of imidazole (Imy) and CCI, was studied in dimethyl sulfoxide (DMSO) at 60°C. The rate of polymerization (R,) is sensitive t o the [CCl,] up to a concentration of 0.60 mol L-I, but at a higher concentrat