𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Living polymerization of methyl methacrylate by novel samarium-based trifunctional initiator

✍ Scribed by Mamiko Narita; Ryoji Nomurat; Ikuyoshi Tomita; Takeshi Endo

Book ID
106002705
Publisher
Springer
Year
2000
Tongue
English
Weight
99 KB
Volume
45
Category
Article
ISSN
0170-0839

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Anionic polymerization of methyl methacr
Anionic polymerization of methyl methacrylate initiated by thiophenol
✍ Makoto Takeishi; Norikazu Iwasaki; Atsushi Sone; Yuichi Chisaka; Kenichi Sekiya; πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 489 KB

## Abstract Methyl methacrylate (MMA) was polymerized by thiophenol without oxidants. Hydroquinone had no effect on the polymerization, indicating that the polymerization proceeded via a non‐radical process. Since other monomers with an __x__,β‐unsaturated carbonyl group polymerized similarly, the

Polymerization of Methyl Methacrylate In
Polymerization of Methyl Methacrylate Initiated by a Divalent Samarium Phenoxide Complex with an Alkyl Aluminium Compound
✍ Mitsufumi Nodono; Toru Tokimitsu; Takayuki Makino πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 131 KB

## Abstract A divalent samarium complex that bears two bulky phenoxide ligands promotes the living polymerization of methyl methacrylate in the absence of cocatalyst. The initiation involves a tail‐to‐tail coupling reaction of the samarium‐enolate radical followed by a one‐electron reduction of the