Novel Binuclear Cobalt Dioxygen Complex—A Step on the Path to Dioxygen Activation
✍ Scribed by Dr. Olivia M. Reinaud; Dr. Glenn P. A. Yap; Prof. Dr. Arnold L. Rheingold; Prof. Dr. Klaus H. Theopold
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 273 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Theoretical studies on the chemo‐ and regioselective __ortho__‐oxidation reaction of phenols mediated by a biomimetic (__μ–η__^2^:__η__^2^peroxo)dicopper(II) complex were performed using unrestricted hybrid density functional theory (UB3LYP) calculations, with the aim of providing a gui
The residue was extracted with Et,O (50 nil) to give a suspension of the red solid product in Et,O. The product was then filtered off and dried in vacuo (31 Yo). Recrystallization of the powder from Et,O:pyridine (90.10) yielded red crystals suitable for X-ray diffraction. Elemental analysis calcd f