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Novel and Stereocontrolled Synthesis of (.+-.)-Tetrodotoxin (I) from myo-Inositol.

โœ Scribed by Ken-ichi Sato; Shoji Akai; Naoki Sugita; Tadatsugu Ohsawa; Tomokazu Kogure; Hirotsugu Shoji; Juji Yoshimura


Publisher
John Wiley and Sons
Year
2006
Weight
10 KB
Volume
37
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereoselective Syn
โœ D. DUBREUIL; J. CLEOPHAX; M. VIEIRA DE ALMEIDA; C. VERRE-SEBRIE; J. LIAIGRE; G. ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 41 KB ๐Ÿ‘ 2 views

Stereoselective Synthesis of 6-Deoxy and 3,6-Dideoxy-D-myo-inositol Precursors of Deoxy-myo-inositol Phosphate Analogues from D-Galactose. -The key step in the synthesis of the title compounds is the Ferrier rearrangement of pyranoside (II). Both resulting cyclohexanones (III) and (IV) can be trans