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Novel and facile reduction of phenol derivatives with samarium diiodide-base system

✍ Scribed by Yasuko Kamochi; Tadahiro Kudo


Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
305 KB
Volume
35
Category
Article
ISSN
0040-4039

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Free radical fragmentation of photoadduc
✍ Gordon L. Lange; Christine Gottardo πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 French βš– 232 KB

Fragmentation of unsaturated photcadduct derivatives 5 and 8 with (n-Bu)@H, (C,H,),SnH or SmI, generally gives mixtures of regioisomers. Sml, is the reagent of choice for these transformations because the yields me high (>90%) and with e&xx &t/b only one isomer, Ilalb, is obtained.