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Novel alkylation with tetrathiotungstates and tetrathiomolybdates: facile synthesis of disulfides from alkyl halides

✍ Scribed by Dhar, Preeti; Chandrasekaran, Srinivasan


Book ID
121289504
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
302 KB
Volume
54
Category
Article
ISSN
0022-3263

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A novel synthesis of thiazoles from dime
✍ C. Alvarez-Ibarra; E. DΓ‘vila; A. Mateo; P. Ortiz; M.L. Quiroga πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 225 KB

We report a new synthesis of thiazoles froma cyclocondensationreactionbetweendimethyl N-(ethoxycarbonylmethyl)iminodithiocarbonate (EMIC), carbon disulfide and alkylation of intel mediate thiazole-Z-thiolate with alkyl halides. We have recently studied the reaction of carbanion fromdimethyl N-(etho