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A novel synthesis of thiazoles from dimethyl N-(ethoxycarbonylmethyl)imino dithiocarbonate, carbon disulfide and alkyl halides

✍ Scribed by C. Alvarez-Ibarra; E. Dávila; A. Mateo; P. Ortiz; M.L. Quiroga

Book ID
104228236
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
225 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis

We report a new synthesis of thiazoles froma cyclocondensationreactionbetweendimethyl N-(ethoxycarbonylmethyl)iminodithiocarbonate (EMIC), carbon disulfide and alkylation of intel mediate thiazole-Z-thiolate with alkyl halides.

We have recently studied the reaction of carbanion fromdimethyl N-(ethoxy carbonylmethyl)iminodithiocarbonate (EMIC) 1,2 2,3 with aromatic aldehydes

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## Abstract magnified image The reaction of oxiranes with carbon disulfide for preparation of cyclic dithiocarbonates was carried out in water under catalytic amount of an organic base such as dimethylaminopyridine or triethylamine. The reaction conditions are simple and give high yields of desire