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Novel 2-Phosphabicyclo[2.2.2]oct-5-ene Derivatives and Their Use in Phosphinylations.

✍ Scribed by Gyoergy Keglevich; et al. et al.

Publisher
John Wiley and Sons
Year
2004
Weight
74 KB
Volume
35
Category
Article
ISSN
0931-7597

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Novel 2-phosphabicyclo[2.2.2]oct-5-ene d
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A 2-phosphabicyclo[2.2.2]oct-7-ene oxide (2) and a 2-phosphabicyclo[2.2.2]octa-5,7-diene oxide (3) with ethyl substituent on the phosphorus atom was synthesized and their fragmentation properties were studied. The phosphabicyclooctadiene oxide (3) could be utilized in both the UV light-mediated phos