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2-Ethyl-2-phosphabicyclo[2.2.2]oct-7-ene Derivatives: Synthesis and Use in Fragmentation-Related Phosphorylations.

✍ Scribed by Helga Szelke; Agnes Balint; Erzsebet Kiraly; Krisztina Ludanyi; Janos Kovacs; Gyoergy Keglevich


Publisher
John Wiley and Sons
Year
2005
Weight
17 KB
Volume
36
Category
Article
ISSN
0931-7597

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2-Ethyl-2-phosphabicyclo[2.2.2]oct-7-ene
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A 2-phosphabicyclo[2.2.2]oct-7-ene oxide (2) and a 2-phosphabicyclo[2.2.2]octa-5,7-diene oxide (3) with ethyl substituent on the phosphorus atom was synthesized and their fragmentation properties were studied. The phosphabicyclooctadiene oxide (3) could be utilized in both the UV light-mediated phos

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## Abstract The [4 + 2] cycloaddition of the double‐bond isomers (**__A__** and **__B__**) of dihydrophosphinine oxide **__1__** afforded novel phosphabicyclo[2.2.2]oct‐5‐ene derivates (**__2–4__**), formation of which was justified by PM3 semiempirical calculations. The compounds of dimer type (**

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