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Nouvelle Methode De Synthese d'Olefines Deuteriees En Position Selective

✍ Scribed by J. P. Quintard; M. Pereyre


Publisher
John Wiley and Sons
Year
1978
Tongue
French
Weight
270 KB
Volume
14
Category
Article
ISSN
0022-2135

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✦ Synopsis


c o w s de l a LibGration, 33405 -TALENCE (France).


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## Abstract A new synthesis of β‐hydroxyesters involving a reaction between a carbonyl compound, ketene and an alkyl‐orthotitanate is described. The following carbonyl compounds have been studied: aldehydes, ketones, α‐diketones, α‐ or γ‐ketoesters. A reaction mechanism is proposed.