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Notes. Polar, Resonance, and Steric Effects of the 2,3-Benzo Substituent

✍ Scribed by Packer, J; Vaughan, J; Wong, E

Book ID
127147101
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
351 KB
Volume
23
Category
Article
ISSN
0022-3263

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## Abstract The rate constants for 3‐substituted adamantyl __p__‐toluenesulfonates **3a**‐**3k** in ethanol/water 80:20 correlate well with the respective inductive substituent constants Οƒ. The reaction constant ρ for the toluenesulfonates **3** is 10% larger than for the corresponding bromides **2