Notes on the mechanisms for aquation and base hydrolysis of acidopentaamminerhodium(III) complexes
β Scribed by H.K.J. Powell
- Publisher
- Elsevier Science
- Year
- 1972
- Weight
- 188 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0020-1650
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Azide anation and racemiration of optically pure mer-ao(H)-and n~er-endo(H)-[Co(OH)(dien)(dapo)]~+ (A and B (X = OH), resp.; dien = N-(2-aminoethyl)ethane-l Jdiamine; dapo = I ,3-diaminopropan-2-oI) involve the same symmetrical pentacoordinate intermediate as the base hydrolyses of the corresponding