Base hydrolysis and aquation of trans-methyl-substituted acidopenta-amminecobalt(III) complexes
✍ Scribed by Fabian Benzo; Adriana Massaferro; Marcelo Queirolo; Beatriz Sienra; Alberto L. Capparelli; Daniel O. Mártire
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 513 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0277-5387
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Rate constants for the hydrolysis (__k__~h~) of six different amines in __trans‐__[Co((BA)~2~en)(amine)~2~]ClO~4~ complexes (amine = aniline 1a, para‐toluidine 1b, benzylamine 1c (primary amines), pyrrolidine 2a, piperidine 2b, morpholine 2c (secondary amines), and (BA)~2~en = Bisbenzoy
The kinetics of base hydrolysis and of aquation of some iron(II)-diimine complexes in the presence of stereoisomeric carbohydrates were monitored spectrophotometrically at 25.0 °C. In basic aqueous solution dissociation of both Fe(1,10-phenanthroline) 3 2 and Fe(2,2'-bipyridine) 3 2 is accelerated w