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Notes - Addition of Alkyl Orthoformates to Olefin Oxides

✍ Scribed by Dermer, O.; Slezak, Frank

Book ID
121328925
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
294 KB
Volume
22
Category
Article
ISSN
0022-3263

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**The presence of a negative partial charge on the benzylic carbon atom in the transition state** __(1)__ can be deduced from the experimentally determinable Hammett Ο± values. Alkyl radicals R^Λ™^ are accordingly seen to develop nucleophilic properties during addition to olefins. equation image