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Note on EPR study of decomposition of polymeric hydroperoxide with polyamines in styrene

✍ Scribed by D. Mikulášová; K. Horie; A. Tkáč

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
213 KB
Volume
10
Category
Article
ISSN
0014-3057

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✦ Synopsis

Decomposition of polyprop.~lenc hydroperoxide in styrene with triethylenetetramine, diethylenetriamine and ethylenediamine at 23-80-was studied by electron paramagnetic resonance measurements. The hfs parameters for isotropic EPR spectra of aminoalkylnitroxy radicals from these polyamines were determined. The supposed complex formation of polymeric hydroperoxide with polyamine by two hydrogen bondings facilitates its decomposition with styrene.

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