Nonracemic α-Fluoro Aldehydes: Asymmetric Synthesis of 4-Deoxy-4-fluoro-D-arabinopyranose. -The first enantioselective synthesis of epimerizable α-fluoro aldehyde (V) and its utility as chiral building block by the asymmetric synthesis of the title pyranose (XI) is described. The precursor for alde
✦ LIBER ✦
Nonracemic α-Fluoro Aldehydes: Asymmetric Synthesis of 4-Deoxy-4-fluoro- d -arabinopyranose
✍ Scribed by Davis, Franklin A.; Kasu, Parimala V. N.; Sundarababu, Gajendran; Qi, Hongyan
- Book ID
- 120562663
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 166 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0022-3263
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The function of carbohydrates in biological systems has been the topic of intensive study. Most recently, glycoprotein recognition has been reported to be essential in cellular trafficking', viral infectivity', cancer metastasis3, and immunological regulation4. Given these important roles and the po