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Nonpolar contributions to the rate of nucleophilic displacements of p-nitrophenyl esters in micelles

โœ Scribed by Gitler, Carlos.; Ochoa-Solano, Armando.

Book ID
120360160
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
742 KB
Volume
90
Category
Article
ISSN
0002-7863

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The ฮฑ-effect in micelles: Nucleophilic substitution reaction of p-nitrophenyl acetate with N-phenylbenzohydroxamate ion
โœ Kallol K. Ghosh; Jyoti Vaidya; Manmohan Lal Satnami ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 118 KB

## Abstract Pseudoโ€firstโ€order rate constants have been determined for the nucleophilic substitution reactions of __p__โ€nitrophenyl acetate with __p__โ€chlorophenoxide (4โ€ClC~6~H~4~O^โˆ’^) and __N__โ€phenylbenzohydroxamate (C~6~H~5~CON(C~6~H~5~)O^โˆ’^) ions in phosphate buffer (pH 7.7) at 27ยฐC. The effec