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Catalysis in ester cleavage. I. Nucleophilic catalysis by acetate ion in the methanolysis of p-nitrophenyl acetate

โœ Scribed by Schowen, Richard L.; Behn, Cherie Gass.


Book ID
127346240
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
747 KB
Volume
90
Category
Article
ISSN
0002-7863

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## Abstract Pseudoโ€firstโ€order rate constants have been determined for the nucleophilic substitution reactions of __p__โ€nitrophenyl acetate with __p__โ€chlorophenoxide (4โ€ClC~6~H~4~O^โˆ’^) and __N__โ€phenylbenzohydroxamate (C~6~H~5~CON(C~6~H~5~)O^โˆ’^) ions in phosphate buffer (pH 7.7) at 27ยฐC. The effec