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Nonmetal-Mediated Fragmentation of P4: Isolation of P1 and P2 Bis(carbene) Adducts

✍ Scribed by Olivier Back; Glenn Kuchenbeiser; Bruno Donnadieu; Guy Bertrand


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
311 KB
Volume
121
Category
Article
ISSN
0044-8249

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The reaction of one equivalent of In with a molten flux of (Ph 4 P) 2 Se 5 and P 2 Se 5 (1 : 2), at 250 Β°C gave the (Ph 4 P)[In(P 2 Se 6 )] (I). Stoichiometric elemental synthesis at 750 Β°C produced the Cs 5 In(P 2 Se 6 ) 2 (II). The thin, yellow crystals of (I), and the irregular, dark orange cryst