Nonlinear structure-reactivity correlation in the pyridinolysis of acetic anhydride
✍ Scribed by Castro, Christian; Castro, Enrique A.
- Book ID
- 126800006
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 648 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
The hydrolysis of 2,4,6-trinitrophenyl acetate was studied in the presence of several carboxylic bases and tertiary amines. Carboxylic bases pyridine and imidazole react as nucleophilic catalysts, while 2,4-dimethyl and 2,4,6-trimethyl pyridine react as general-base catalysts. The nonlinear structur
## Abstract The reaction of the title substrate with a series of amines of varying p__K__~a~, viz. ammonia, ethanolamine, glycine, 1,2‐diaminopropane, 1,3‐diaminopropane, __n__‐butylamine, piperidine, hydrazine, imidazole, and hydroxylamine is subjected to a kinetic study in aqueous medium, 25°C, i