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Structure−Reactivity Relationships in the Pyridinolysis of N -Methyl- N -arylcarbamoyl Chlorides in Dimethyl Sulfoxide

✍ Scribed by Lee, Ikchoon; Hong, Sung Wan; Koh, Han Joong; Lee, Yong; Lee, Bon-Su; Lee, Hai Whang


Book ID
127368491
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
90 KB
Volume
66
Category
Article
ISSN
0022-3263

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The rate of the solvent substitution reaction, CoCl 3 S À +Cl À YCoCl 4 2À +S (S-solvent) has been studied by means of stopped flow spectrophotometry in dimethyl sulfoxide (DMSO) and N,N-dimethylformamide (DMF), and the rate constant k f , and the activation enthalpy D f H p and entropy D f S p have