Nonlinear equivalent circuits for membranes
β Scribed by William F. Pickard
- Book ID
- 104698192
- Publisher
- Springer
- Year
- 1984
- Tongue
- English
- Weight
- 793 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0303-6812
No coin nor oath required. For personal study only.
β¦ Synopsis
The problem of obtaining Helmholtz equivalents for nonlinear resistive one-ports is considered. Two fundamentally different classes of equivalent are described, one local and the other global. For each, necessary and sufficient conditions are derived for the existence and uniqueness of either the ThΓ©venin equivalent or the Norton equivalent or both. These concepts are illustrated (i) by proving that a cell whose channels and pumps are monotone in the membrane potential will, in the absence of net state changes in these ionophores, possess a unique stable resting potential and (ii) by demonstrating that it is in principle impossible to assign unique equivalent circuits to such ionophores.
π SIMILAR VOLUMES
Recently, Macdonald 1 has suggested an equivalent circuit (Fig. 19, ref. 1) for an electrochemical cell where (a) an infinitely rapid faradaic reaction occurs at the electrodes, and (b) an indifferent electrolyte is present. This circuit is at variance with conventional electrochemical thinking and