Nonenzymatic Enantioselective Acylation of Racemic Secondary Alcohols Catalyzed by a SnX2-Chiral Diamine Complex. -Under the optimized conditions shown a kinetic nonenzymatic resolution is achieved with different kinds of racemic secondary alcohols. -(ORIYAMA, T.; HORI,
Nonenzymatic enantioselective acylation of racemic secondary alcohols catalyzed by a SnX2-chiral diamine complex
β Scribed by Takeshi Oriyama; Yoko Hori; Keisuke Imai; Ryosuke Sasaki
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 193 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The polymeric [__N__β²,__N__β²βbis(salicylidene)ethaneβ1,2βdiaminato(2β)]manganese(III) ([Mn^III^(salen)]) type complexes **1** and **2** were successfully applied to the oxidative kinetic resolution of secondary alcohols. The reaction proceeded readily at room temperature with excellent