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Nonclassical Organolanthanoid Metal Chemistry: [K([18]-crown-6)(η 2 -PhMe) 2 ]X (X = [(LnCp t3 ) 2 (μ-H)], [(LnCp‘ ‘ 2 ) 2 (μ-η 6 :η 6 -PhMe)]) from [LnCp x3 ], K, and [18]-crown-6 in Toluene (Ln = La, Ce; Cp t = η 5 -C 5 H 4 SiMe 2 Bu t ; Cp‘ ‘ = η 5 -C 5 H 3 (SiMe 3 ) 2 -1,3)

✍ Scribed by Gun'ko, Yurii K.; Hitchcock, Peter B.; Lappert, Michael F.


Book ID
126305867
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
92 KB
Volume
19
Category
Article
ISSN
0276-7333

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✍ Antonio Antiñolo; Iván Dorado; Mariano Fajardo; Andrés Garcés; Isabel López-Sol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3