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Noncatalytic Beckmann Rearrangement of Cyclohexanone-Oxime in Supercritical Water

✍ Scribed by Sato, Osamu; Ikushima, Yutaka; Yokoyama, Toshirou


Book ID
127265596
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
86 KB
Volume
63
Category
Article
ISSN
0022-3263

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Beckmann rearrangement of cyclohexanone
✍ Avelino Corma; Hermenegildo Garcia; Jaime Primo; Enrique Sastre πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 522 KB

The Beckmann rearrangement of cyclohexanone oxime (1) was carried out in the liquid phase in the presence of a series of acid zeolites (HY-20, HY-50, HY-100, HYD, and HZSM-5) at different reaction temperatures. Together with e-caprolactam (2). 5-cyano-1-pentene (3), and cyclohexanone (4) were prese