A theory of intramolecular non-radiative transitions is proposed for gaseous small molecules. The theory explains three experimental features: the linearity of the Stern-Volmer equation, the Douglas effect, and the fact that the non-radiative rate is faster in a gas than in condensed media.
Non-radiative transition in a potential crossing system
β Scribed by Y. Kayanuma; K. Nasu
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 284 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0038-1098
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The urnmuon amphtudr (tle\p(-IHz)li) IS calculated as 3 reverse Laplacr transformation of the resolvenr (II(E-\_-'I~~ lllc dctermmzmtal perturbntlon e\panslon of Baker and Sasakawa 1s used to glvc the poles and residues of the resolvenr The mtcrsystcm crossmg rate IS calculated between 'A" and 3A' s
This article points out a new aspect of approximate calculations of molecular potential curves\_ Two curves that cross in an exact solution of the ekctronic wave equation may avoid each other when an approsimate method is used. This is in direct contradiction to the usual interpretation of the van N