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Non-radiative transitions in gaseous molecules: intersystem crossing rates of sulfur dioxide

✍ Scribed by K. Takahasih

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 361 KB
Volume: 67
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)85167-2

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✦ Synopsis

A theory of intramolecular non-radiative transitions is proposed for gaseous small molecules. The theory explains three experimental features: the linearity of the Stern-Volmer equation, the Douglas effect, and the fact that the non-radiative rate is faster in a gas than in condensed media.

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