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Non-planar (C2) structure of phthalan from fluorescence spectroscopy in a supersonic jet

โœ Scribed by Karim H. Hassan; J.Michael Hollas

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
425 KB
Volume
169
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Phthalan has been shown, previously, from the observation of far-infrared puckering transitions, to have a planar skeleton in respect to this puckering motion in the S, electronic state. Supersonic jet fluorescence spectra show, however, that the 1,3-carbon atoms are twisted out-of-plane in a Cz configuration with a 137 cm-' barrier to planarity.

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