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Non-linear realizations and effective Lagrangians for chiral symmetry breaking

✍ Scribed by R.B. Jones


Book ID
116139157
Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
459 KB
Volume
34
Category
Article
ISSN
0550-3213

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Non-linear effects operate and dynamic l
✍ Jean Philippe Cros; Yolanda PΓ©rez-Fuertes; Michael J Thatcher; Susumu Arimori; S πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 157 KB

Non-linear effects reveal that the use of chiral BINOL-boron reagents for aza-Diels-Alder reactions results in an enantioselective catalytic species containing at least 2 equiv. of BINOL. Dynamic ligand exchange and ligand accelerated catalysis occurs in these reactions, consistent with the formatio