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Non-hydrolytic cleavage of esters with magnesium iodide in aprotic non-polar solvents

✍ Scribed by A. García Martínez; J. Osío Barcinaa; G. Hidalgo del Veccio; M. Hanack; L.R. Subramanian

Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
213 KB
Volume
32
Category
Article
ISSN
0040-4039

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Complexes between alkaline-earth-metal ions M\*' and cyanate OCN' in aprotic solvents are studied by infrared spectrometry in the v(CN) region (2150-2250 cm-'). In dimethylsulphoxide (DMSO) and hexamethylphosphotriamide (HMPT) isocyanate MNCO ion pairs exhibit a specific v(CN) band while M(NCO)z spe