The mechanistic and synthetic aspects o f the addition reaction of thioxophosphorane sulfenyl bromide with ethyl vinyl ether were studied in detail by N M R techniques. It has been found that the regiospecific, primary product of the reaction, I -bromo-1-ethoxy-2S(dialkoxythiophosphoryl)ethane I , i
β¦ LIBER β¦
Reaction of diphenylcarbenepentacarbonyltungsten with ethyl vinyl ether in non-polar solvents
β Scribed by K. Weiss; K. Hoffmann
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 193 KB
- Volume
- 255
- Category
- Article
- ISSN
- 0022-328X
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## Abstract The intrinsic reactivity of eight gaseous, massβselected 2βazabutadienyl cations toward polar [4^+^ + 2] cycloaddition with ethyl vinyl ether has been investigated by pentaquadrupole mass spectrometric experiments. Cycloaddition occurs readily for all the ions and, with the only excepti
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