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Non-equlibrium kinetics of bimolecular reactions. IV. Experimental prediction of the breakdown of the kinetic mass-action law

✍ Scribed by Heshel Teitelbaum


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
772 KB
Volume
173
Category
Article
ISSN
0301-0104

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Reactions of chiral molecules in the pre
✍ L.D. Barron πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 702 KB

It is suggested that conventional kinetic principles do not apply to processes involving chiral molecules in the presence of a time-non-invariant enantiomorphous influence on account of the breakdown of microscopic reversibility and hence of detailed balancing. This implies different rate constants