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NON-CHAIR CONFORMATIONS. EQUILIBRATION OF CIS- AND TRANS- 2,5-DI-t-BUTYL-1,4-CYCLOHEXANEDIONE

โœ Scribed by Stolow, Robert D.; Boyce, Charles B.

Book ID
126408539
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
259 KB
Volume
83
Category
Article
ISSN
0002-7863

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Equilibration of cis - and trans -2- t -
Equilibration of cis - and trans -2- t -butyl-4-hydroxycyclohexanone
โœ Robert D. Stolow; Theodore Groom ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 204 KB

Equilibrations of the stereoisomeric cis -and trans -2 -t-butyl-4 -hydroxycyclo-hexanones (I and If), catalyzed by hydrogen chloride in benzene solution (Table I), show 'AH", -130 \* 30 Cal/mole; i?S", of log K vs. l/T. -0.13 \* 0.1 eu; from a graph Estimated absolute error limits are given.