𝔖 Bobbio Scriptorium
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Non-activated and activated anionic polymerization of adipimide

✍ Scribed by Toshiyuki Kodaira; Jaroslav Stehlíček; Jan Šebenda

Book ID
103071104
Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
365 KB
Volume
6
Category
Article
ISSN
0014-3057

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✦ Synopsis

A~tract--The ring opening polymerization of adipimide was studied in the presence of sodium adipimide as catalyst and triacetamide as activator. Over the temperature range 120-220 °, the polymer was insoluble in the monomer; therefore the polymerization ceased almost completely as soon as the reaction mixture solidified although the catalyst was still active. Attempts to copolymerize adipimide with 5-and 6-membered cyclic imides yielded polyadipimide only.

📜 SIMILAR VOLUMES

Anionic polymerization of adipimide
Anionic polymerization of adipimide
✍ Wichterle, O. ;Stehlíček, J. ;Kodaira, T. ;Šebenda, J. 📂 Article 📅 1967 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 116 KB
Structure of polymers formed by anionic
Structure of polymers formed by anionic polymerization of adipimide
✍ T. Kodaira; J. Stehliček; J. Šebenda 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 425 KB

Products obtained by an/chic polymerization of adipimide contain foreign structures derived from 6-oxo-1,1 l-andecanedioic acid, as a result of base cataiysed condensation. The decrease in adipimide units, however, is much greater than corresponds to the number of oxod/carboxyfic acid units so that

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