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N,N′ -Dioxide-Magnesium Ditriflate Complex-Catalyzed Asymmetric α-Hydroxylation of β-Keto Esters and β-Keto Amides

✍ Scribed by Yin, Chengkai; Cao, Weidi; Lin, Lili; Liu, Xiaohua; Feng, Xiaoming


Book ID
120421760
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
395 KB
Volume
355
Category
Article
ISSN
1615-4150

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Enantioselective Michael additions of β-
✍ Makoto Nakajima; Satoshi Yamamoto; Yukiko Yamaguchi; Seiichi Nakamura; Shunichi 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 193 KB

A catalytic, enantioselective Michael addition of b-keto esters to a,b-unsaturated carbonyl compounds was achieved by using a chiral biquinoline N,N 0 -dioxide-scandium trifluoromethanesulfonate complex as a catalyst. The corresponding Michael adducts were obtained in high yields and with enantiosel