✦ LIBER ✦

ChemInform Abstract: Axially Chiral C2-Symmetric N-Heterocyclic Carbene (NHC) Palladium Complex-Catalyzed Asymmetric α-Hydroxylation of β-Keto Esters.

✍ Scribed by Shu-Hua Cao; Min Shi

Publisher: John Wiley and Sons
Year: 2011
Weight: 38 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201117022

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✦ Synopsis

Abstract

The asymmetric hydroxylation of indan‐1‐one‐2‐carboxylates using phenyloxaziridine as oxidant is catalyzed by a novel axially chiral NHC—Pd catalyst (BINCAP).

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