✦ LIBER ✦

ChemInform Abstract: Asymmetric Addition of Arylboronic Acids to Cumulene Derivatives Catalyzed by Axially Chiral N-Heterocyclic Carbene—Pd2+ Complexes.

✍ Scribed by Zhen Liu; Peng Gu; Min Shi

Publisher: John Wiley and Sons
Year: 2011
Weight: 72 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201138066

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✦ Synopsis

Abstract

The method affords allenes which can be further transformed on a 2 mmol scale into dihydropyrans or an aldehyde without loss of enantioselectivity.

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ChemInform Abstract: Catalytic Asymmetri

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ChemInform Abstract: Catalytic Asymmetri

ChemInform Abstract: Catalytic Asymmetric Addition of Arylboronic Acids to N-Boc Imines Generated in situ Using C2-Symmetric Cationic N-Heterocyclic Carbenes (NHCs) Pd2+ Diaquo Complexes.

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ChemInform Abstract: Axially Chiral C2-S

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## Abstract The asymmetric hydroxylation of indan‐1‐one‐2‐carboxylates using phenyloxaziridine as oxidant is catalyzed by a novel axially chiral NHC—Pd catalyst (BINCAP).