In the title compound, C 24 H 38 N 2 O 6 S 2 , which was synthesized from (+)-10-camphorsulfonic acid chloride and piperazine, the central piperazine ring adopts a chair conformation. The two camphorlsulfonyl groups are bound to the piperazine N atoms in equatorial positions. The molecule has approx
N,N′-Dimethylpiperazinium(2+) bis[methylenehydrogendiphosphonate(1−)]
✍ Scribed by Yuan, Zhanhui ;Clegg, William
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 202 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, C 23 H 17 N 5 O 2 S 2 ÁC 3 H 7 NO, hydrogen bonds involving the amide groups and the pyridine N atoms force the two carboxamide groups and the central pyridine ring into the same plane. The solvent molecule is stabilized in the cavity formed by the two arms of the molecule by
The title complex, [Cu 2 (N 3 ) 4 (C 5 H 14 N 2 ) 2 ], is a centrosymmetric dimer in which each Cu atom is coordinated by five N atoms from three azide anions and one N,N-dimethyl-1,3-propylenediamine molecule in a distorted square-pyramidal geometry; the CuÁ Á ÁCu distance is 3.416 (1) A ˚.
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.002 A Ê R factor = 0.036 wR factor = 0.100 Data-to-parameter ratio = 12.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.