Aqua[2,2 0 0 0 -(naphthalene-2,3-dioxy)bis(N,N-diethylacetamide)]trinitratocerium(III) acetonitrile solvate
[N,N-Diisopropyl-2,2′-(2,3-naphthalenedioxy)diacetamide]trinitratoneodymium(III) acetone solvate
✍ Scribed by Lei, Ke-Wei ;Liu, Wei-Sheng ;Yu, Kai-Bei
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 211 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Nd(NO 3 ) 3 (C 26 H 38 N 2 O 4 )]ÁC 3 H 6 O, the Nd III atom is coordinated by ten O atoms in a a distorted bicapped dodecahedral geometry. The Nd-O(carbonyl) bond distances [average 2.3817 (18) A ˚] are significantly shorter than other Nd-O bonds in the Nd III complex.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 193 K Mean '(C±C) = 0.002 A Ê R factor = 0.039 wR factor = 0.102 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Re(C 7 H 12 NO 2 S 3 )(C 18 H 15 P)]ÁC 3 H 6 O, crystallizes from a solution in chloroform-acetone-cyclohexane with enantiomers disordered equally over each molecular site. Hydrogen bonds between the carboxyl groups form dimers in the crystal structure.