Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.005 A Ê R factor = 0.033 wR factor = 0.078 Data-to-parameter ratio = 25.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
(N,N-Diethyldithiocarbamato)(tricyclohexylphosphine)gold(I)
✍ Scribed by Ho, Soo Yei ;Tiekink, Edward R. T.
- Publisher
- International Union of Crystallography
- Year
- 2001
- Tongue
- English
- Weight
- 223 KB
- Volume
- 57
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.008 A Ê R factor = 0.042 wR factor = 0.115 Data-to-parameter ratio = 28.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
resulting white precipitate was ®ltered, washed with cold ethanol and dried in vacuo. Crystals suitable for X-ray analysis were obtained by recrystallization from a 1:1 mixture of ethanol and chloroform.
The title compound, [Sn(C 6 H 5 ) 3 {S 2 CN(Et)C 6 H 11 }], has a similar geometry to its methyl analogue, between tetrahedral and distorted trigonal bipyramidal but closer to the latter. The long intramolecular SnÁ Á ÁS interaction of 2.9426 (10) A Ê is slightly shorter than in its methyl analogue,
Single-crystal X-ray study T = 203 K Mean '(C±C) = 0.018 A Ê R factor = 0.051 wR factor = 0.149 Data-to-parameter ratio = 19.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.032 wR factor = 0.081 Data-to-parameter ratio = 23.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.