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[N,N′-Bis(salicylidene)benzene-1,2-diaminato]iron(II)

✍ Scribed by Ye, Yong-Hao ;Han, Yue ;Chen, Ting-Ting ;Liu, Chang-Hong


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
586 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title complex (systematic name; {2,2

is a mononuclear iron(II) complex with a distorted squareplanar coordination geometry. The central Fe 2+ ion is fourcoordinated by two O and two N atoms from a Schiff base ligand, which is obtained by condensing 1,2-diaminobenzene and two equivalents of salicylaldehyde in acetonitrile.


📜 SIMILAR VOLUMES


[N,N′-Bis(pyrrol-2-ylmethylene)cyclohexa
✍ Chen, Jia-Mei ;Ruan, Wen-Juan ;Gao, Feng ;Zhang, Ying-Hui ;Zhu, Zhi-Ang 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 493 KB

The tetradentate Schiff base ligand derived from the condensation of pyrrole-2-carbaldehyde and cyclohexane-1,2-diamine forms a square-planar four-coordinate Ni complex, [Ni(C 16 H 18 N 4 )]. The compound crystallizes with two crystallographically independent molecules in the asymmetric unit.