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{N,N-Bis­[(diphenyl­phosphino)meth­yl]­aniline}tetra­carbonyl­molybdenum(0)

✍ Scribed by Sanchez Ballester, Noelia M. ;Elsegood, Mark R. J. ;Smith, Martin B. ;Brown, Gavin M.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
163 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Mo(CO)~4~{Ph~2~PCH~2~N(Ph)CH~2~PPh~2~}] or [Mo(C~32~H~29~NP~2~)(CO)~4~], is a tetracarbonylmolybdenum(0) complex of a chelating ditertiary phosphine with a P—C—N—C—P backbone. The geometry at the Mo centre is octahedral, while both diphenylphosphino centres coordinate in a cis fashion.

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