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NMR study of high-Tc superconductors

โœ Scribed by K. Asayama; G.-Q. Zheng; Y. Kitaoka; K. Ishida; K. Fujiwara


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
399 KB
Volume
178
Category
Article
ISSN
0921-4534

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โœฆ Synopsis


From systematic measurements of TI, Knight shift, NQR frequency of 63Cu and ~70 with high-pressure measurement in high-Tc materials, La2_;,SrxCuO4, YBa2Cu307 and T12Ba2CuO6+ e the following results have been obtained. The staggered susceptibility at the zone boundary, X(Q) which is a measure of the antiferromagnetic spin fluctuation decreases in order of the La, Y and T1 system. X(Q) is governed by the number of Cu d-holes, n (Cu) and O p-holes, n (O) in the CuO2 plane, x(Q) increases when n(Cu)/n(O) increases. Tc increases and then decreases with n(Cu)/n(O) having a maximum at an optimum value of n(Cu)/ n (O). Correlation between X(Q) and Tc has been discussed by assuming X(Q) to play an essential role for the occurrence of high-Tc superconductivity. The T-dependence of 1/Tt below Tc suggests strongly the d-wave pairing model.


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The superconducting property of YBa2(CUl\_xHx)307 {H=Zn and Ni) has been investigated by 63Cu NQR and NMR techniques. In case of Zn(3d I0) doped into CuO 2, the residual spin Knight shift of 63Cu increases appreciably with increasing concentration. Correspondingly,TIT=const. law holds far below Tc,