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NMR and NQR studies of high Tc superconductors

✍ Scribed by W.W. Warren Jr.; R.E. Walstedt; R.F. Bell; G.F. Brennert; R.J. Cava; G.P. Espinosa; J.P. Remeika


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
330 KB
Volume
153-155
Category
Article
ISSN
0921-4534

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✦ Synopsis


63'65Cu NMR and NQR studies of YBa2Cu307_ b are described for compositions, 6, of 0.0, 0.3, and 0.9. Spin-lattice relaxation rates in YBazCu307 reveal significantly different electron dynamics at the two Cu sites in both the normal and superconducting states. In YBa2Cu306.7, the relaxation rates of the sites giving a 31 MHz NQR line are dramatically lower (by a factor ~ 1/1500) than in YBa2Cu307 indicating the essential vanishing of mobile carrier density on these sites. In contrast, relaxation at the 22 MHz sites is reduced only about 30 %. Interpretation of these and other NMR and NQR data is discussed in relation to the question of assignment of the NQR lines to the appropriate crystalline sites.


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From systematic measurements of TI, Knight shift, NQR frequency of 63Cu and ~70 with high-pressure measurement in high-Tc materials, La2\_;,SrxCuO4, YBa2Cu307 and T12Ba2CuO6+ e the following results have been obtained. The staggered susceptibility at the zone boundary, X(Q) which is a measure of the