The thermally induced inverse helix-coil transition of poly(7-benzyl-L-glutamate) (PBLG) in dichloroacetic acid/l,3-dichloropropane, dichloroacetic acid/l-chlorobutane and dichloroacetic acid/l-chlorooctane solvent systems was studied using sensitive differential microcalorimetry. A negative heat ca
N.m.r. studies of the helix-coil transition of polypeptides in non-protonating solvent mixtures
✍ Scribed by E.M Bradbury; C Crane-Robinson; L Paolillo; P Temussi
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 521 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0032-3861
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The thermally induced coil-helix transition of poly(y-benzyl-cglutamate) (PBLG) and poly(y-methyl-Lglutamate) (PMLG) in binary solvent mixtures was investigated by calorimetric and optical rotatory dispersion (ORD) measurements. Dichloroacetic acid was the common active solvent, and the inert solven
## Abstract Using the formalism of nearest‐neighbor Ising model and assuming that the allowed states for a monomeric unity of a polypeptide chain in solutions containing strong acids are E (helix), C (coil), and CS (solvent‐bonded coil), the partition function of the system was deduced analytically