## Abstract ^23^Naβchemical shifts for the NaClO~4~ solute depend markedly upon the composition of binary solvent mixtures of THF with amines (pyridine, piperidine, pyrrolidine, aniline, propylamine, and isopropylamine). These changes, analyzed in a novel application of the __Hill__ formalism, show
NMR studies of preferential solvation of sodium cation in mixtures of N-methylformamide with water and some nonaqueous solvents
β Scribed by Huey-Jan Chuang; Lee-Lin Soong; George E. Leroi; Alexander I. Popov
- Publisher
- Springer US
- Year
- 1989
- Tongue
- English
- Weight
- 543 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0095-9782
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Equivalent conducfances of Bu4NN03, AgNO. and Kl in methanol (MeOH) and those of Bu4NBPh4, Bu+NNOs, ByNI, AgNOs and KI in several N,N-dimethylformamide+methanol (DMF + MeOH) mixtures over the entire solvent composition range have been measured at 25Β°C. The conductance data in ail the case-s have bee
A general equation which relates the dissociation constant of an acid with the solvent composition in binary solvent mixtures is derived. The equation considers that the two solvents interact to form mixed structures. The electrolyte interacts with the mixed solvent formed and with the two pure solv