Deviations from the generality of the βm
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Martin W. Bredenkamp; Adriaan Wiechers
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Article
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1987
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Elsevier Science
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French
β 211 KB
The general use of mass spectrometry for determining the mode of ester attachment in pyrrolizidine alkaloids is based on what appears to be an over simplification of complex fragmentation pathways, and seems to produce unreliable results when applied to macrocyclic pyrrolizidine alkaloids.