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Deviations from the generality of the ‘mass spectrometric method’ for determining the mode of ester attachment in pyrrolizidine Alkaloids

✍ Scribed by Martin W. Bredenkamp; Adriaan Wiechers

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
211 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis

The general use of mass spectrometry for determining the mode of ester attachment in pyrrolizidine alkaloids is based on what appears to be an over simplification of complex fragmentation pathways, and seems to produce unreliable results when applied to macrocyclic pyrrolizidine alkaloids.

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