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NMR spectroscopy with radial pulses. p- and n-type selection COSY

✍ Scribed by D.G. Cory; F.H. Laukien; W.E. Maas

Book ID
103035166
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
427 KB
Volume
212
Category
Article
ISSN
0009-2614

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✦ Synopsis

A novel NMR probe geometry is introduced and shown to have advantages for coherence pathway selection. The probe can generate rf fields with two distinct symmetries, a normal homogeneous rf field, and a "radial" rf field. One field can be used to both excite and detect the spin magnetization while the other is used to introduce spatially varying coherence pathway transformations. The detection process will select only that magnetization that preserves the symmetry of the detection coil. A single acquisition quadraturedetected COSY experiment is shown as an example of this principle.

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